Preheat oven to 350°F (175°C). Grease an 8-inch round cake pan and line the bottom with parchment paper.
Mix dry ingredients: In a medium bowl, whisk together flour, cornstarch, black cocoa, baking powder, baking soda, and salt. Set aside .
Combine wet ingredients: In another bowl, whisk together sugar, canola oil, eggs, sour cream, buttermilk, vanilla extract, espresso powder, and hot coffee.
Incorporate dry and wet: Add dry ingredients to wet in two batches, folding gently until combined. Avoid overmixing to keep the cake tender.
Pour batter into prepared pan. Smooth the top and bake 25–30 minutes, or until a toothpick inserted in the center comes out clean.
Let cake cool in pan for 10 minutes, then transfer to a wire rack to cool completely before frosting.