Preheat the oven to 425°F. Grease 6 jumbo muffin wells or line them with jumbo muffin liners.
Brown the butter by placing it in a saucepan over medium heat. Cook, stirring occasionally, until the butter foams and the milk solids turn golden brown and smell nutty. Immediately transfer the browned butter to a heatproof mixing bowl and let it cool until warm but no longer hot.
Add the granulated sugar and brown sugar to the browned butter. Beat until well combined.
Add the canola oil, sour cream, whole milk, vanilla, and eggs. Mix until smooth and well combined.
In a separate bowl, whisk together the flour, baking powder, baking soda, salt, cinnamon, and espresso powder, if using.
Add the dry ingredients to the wet ingredients and mix just until combined. Being careful not to overmix.